Difference between boiling points and intermolecular forces
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where T b is the boiling-point elevation, or the difference between the boiling point of the solution and that of the pure solvent; i is the van’t Hoff factor; K b is a constant that is characteristic of the solvent and is called the molal boiling-point elevation constant; and m solute is the molality of the solute in the solution.
Jun 30, 2013 · Differences in dispersion forces are negligible because these two molecules don't differ very much in terms of surface area so you can ignore that. You can also note that that the difference in boiling point is not big so that slight difference in mass accounts for only a slight difference in boiling point.